Methane Oxidizes–sho nuff?

So one of our genius crew, Dave, put up a comment that has me all disturbed and that ain’t good at my advanced age.

In response to my post on Methane and a few of my comments about how little methane there is and there are plenty of natural sources of methane,
Dave says this
daveburton | February 17, 2014 at 2:05 pm | Reply | Edit
Even if you don’t burn it, methane (CH4) in the atmosphere oxidizes fairly rapidly, changing into (negligible amounts of) harmless CO2 and water:
CH4 + 2·O2 -> CO2 + 2·H2O
Various sources give the half-life of methane in the atmosphere as 6 to 8 years, which would make the average lifetime 1.4427 times that (because oxidation is an exponential process, rather than linear), yielding an average lifetime for a molecule of CH4 in the atmosphere of 8.7 to 11.5 years. Page 11 of this source gives the directly-calculated atmospheric lifetime of CH4 as ~8 years, but identifies a feedback mechanism that (they say) effectively increases the atmospheric lifetime of additional CH4 to ~12 years.
Call it 8-12 years. That’s pretty short. It means the only reason methane levels are as high as they are (about 1.8 ppm) is that methane emissions are already high. There would have to be a very large, sustained increase in methane emissions to cause much increase in long-term average atmospheric methane levels.
john1282 | February 17, 2014 at 4:27 pm | Reply | Edit
Dave, help me- how could a subtance that oxidizes easily have a half life of 8-12 years unless the people who claim that, like EPA junk scientists, are messin’ with our minds?
Did you know we have some hot damn chemists. Mr. Bob is a chemist tadchem is a chemist, I presume.
Who knows how many chemists we have? I am putting this up for comment as a post to get your comment some attention.
I will find out, won’t I? Your comment goes up as a post.

2 thoughts on “Methane Oxidizes–sho nuff?”

  1. With methane at 1.8ppm, and oxygen at only 200,000ppm, perhaps the methane molecules are slow to decide which oxygen molecules to pair up with.
    More seriously, here’s a paper on oxidation: Almost all of these discussions are of biological involvement:
    https://microbewiki.kenyon.edu/index.php/Nitrate/nitrite_methane_oxidation
    The redox discussion in Wikipedia is helpful:
    http://en.wikipedia.org/wiki/Redox
    Wikipedia’s discussion of atmospheric methane notes:

    Methane is created near the surface, and it is carried into the stratosphere by rising air in the tropics. Uncontrolled build-up of methane in Earth’s atmosphere is naturally checked—although human influence can upset this natural regulation—by methane’s reaction with hydroxyl radicals formed from singlet oxygen atoms and with water vapor.

    ===|==============/ Keith DeHavelle

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